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اطلاعات دوره: 
  • سال: 

    2019
  • دوره: 

    11
  • شماره: 

    7
  • صفحات: 

    892-912
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    206
  • دانلود: 

    0
چکیده: 

In this study novel tetra furfurylamide substituted metal phthalocyanine (M=Co, Cu, Ni & Zn) were synthesized and characterized by elemental analysis, Ultra-violet, Fourier transfer infrared spectroscopy, mass spectroscopy and powder X-ray diffraction analysis. The cobalt (II) tetra furfurylamide phthalocyanine (CoTfurNH2Pc) tailored GCE was constructed by drop covering technique. The fabricated electrode was subjected for electrochemical investigation of oxidizable species such as dopamine (DA), uric acid (UA) and reducible moiety like dimetridazole (DMZ). It was noticed that CoTfurNH2Pc/GCE exhibits admirable electrochemical performance for dopamine, uric acid oxidation and dimetridazole reduction in PBS pH 7. 0. The sensor exhibits sensitivity for DA (CV 0. 179, DPV 0. 333, CA 0. 486 μ A μ M-1cm-2), for UA (CV 0. 517, DPV 0. 374, CA 0. 129 μ A μ M-1cm-2), for DMZ is (CV-8. 55, DPV-13. 73, CA-0. 393 μ A μ M-1cm-2) respectively (S/N=3). Biomolecules present in same solution can be sensed by constructed electrode with peaks resolution of 348 millivolts and 318 millivolts for dopamine-dimetridazole and dimetridazole-uric acid respectively. The CoTfurNH2Pc fabricated electrode has various useful properties like high repeatability, quick response and steadiness. Further DPV and chronoamperometric of titled compound has been studied.

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بازدید 206

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اطلاعات دوره: 
  • سال: 

    2014
  • دوره: 

    11
تعامل: 
  • بازدید: 

    414
  • دانلود: 

    0
چکیده: 

VANADIUM REDOX FLOW BATTERY (VRFB) IS A NEW ENERGY STORAGE SYSTEM WHICH HAS VARIOUS ADVANTAGES, SUCH AS LONG CYCLE LIFE, HIGH EFFICIENCY, FLEXIBLE DESIGN, HIGH RELIABILITY, LOW MAINTENANCE COSTS AND ENVIRONMENTAL FRIENDSHIP. THE FOLLOWING EQUATIONS SHOW THE HALF-REACTIONS OF POSITIVE AND NEGATIVE ELECTRODE IN CHARGING MODE:POSITIVE HALF CELL: VO2++H2O®VO2++2H++2E-NEGATIVE HALF CELL: V3++E-®V2+THE USE OF THIS SYSTEM ALONG WITH SOLAR POWER, WIND AND THERMAL POWER PLANTS, ETC. HAS GROWN SIGNIFICANTLY. DUE TO THE ACTUAL AND POTENTIAL BENEFITS OF THIS TECHNOLOGY, A GREAT FUTURE IS PREDICTED FOR THIS TECHNOLOGY. CURRENTLY, THE MATERIALS USED IN VRBS INCLUDE POLYMER-IMPREGNATED GRAPHITE PLATES, CONDUCTIVE CARBON-POLYMER COMPOSITES AND POLYMER-IMPREGNATED FLEXIBLE GRAPHITE. THE METHODS THAT HAVE BEEN DEVELOPED TO MODIFY THE GRAPHITE FELT MAINLY INCLUDE HEAT TREATMENT, CHEMICAL TREATMENT, ELECTROCHEMICAL OXIDATION AND DOPING BY DEPOSITING OTHER METALS ON CARBON FIBERS. THE PURPOSE OF THIS STUDY IS DESIGNING AND FABRICATION OF VANADIUM BATTERY MONO-CELL USING OF CARBON NANOTUBE (CNT) AS THE ELECTRO-CATALYST BECAUSE OF THE HIGH SURFACE AREA AND GOOD ELECTRICAL CONDUCTIVITY OF THIS MATERIAL. CARBON NANOTUBE WAS LOADED ON THE CARBON FELT ELECTRODE BY SONICATING THE ELECTRODE FLOATED IN THE CNT INK FOR APPROPRIATE TIME. RESULTS INDICATE THAT LOADING OF CARBON NANOTUBE ON CARBON FELT ELECTRODE AND THEN APPLYING HEAT-ACID TREATMENT ON CNT-MODIFIED FELT ELECTRODES CAN GREATLY IMPROVE THE PERFORMANCE OF ELECTRODE FOR USING IN VANADIUM REDOX FLOW BATTERY. ALL OF THE EFFECTIVE PARAMETERS SUCH AS CNT INK COMPOSITION, FLOATING TIME AND TIME OF THERMAL TREATMENT WERE OPTIMIZED. BY USING THE CNT-MODIFIED FELT ELECTRODE VRFB MONO-CELL WAS DESIGNED. WE USED TWO SEPARABLE PUMPS WHICH CAN PUMP POSITIVE AND NEGATIVE ELECTROLYTES WITH THE SAME ELECTROLYTE FLOW RATE OF 50 ML/MIN.BTHE EFFECTIVE AREA OF THE CELL IS DEFINED BY THE EFFECTIVE AREA OF 5 CM2 OF GRAPHITE FELT ELECTRODES WITH 3.18 MM THICKNESS. THE MEMBRANE USED IN THE CELL IS NAFION 117. MEMBRANE TREATMENT, DESIGNING AND MONO-CELL ASSEMBLING HAS BEEN DONE IN THE NANO TECHNOLOGY LABORATORY OF ISFAHAN UNIVERSITY.

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نویسندگان: 

MOULAY S.

نشریه: 

IRANIAN POLYMER JOURNAL

اطلاعات دوره: 
  • سال: 

    2001
  • دوره: 

    10
  • شماره: 

    2
  • صفحات: 

    77-83
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    451
  • دانلود: 

    0
چکیده: 

Study of the removal of blocking groups in redox polymer precursors, poly(5-vinyl-1, 3-benzodioxole) (polymer 1) and poly(2, 3-dimethoxystyrene) (polymer II), was undertaken with different acidic reagents. Boron trichloride dodecyl mercaptan (RSH) system showed a better cleaving performance among the experimented reagents. Poly(4-vinylcatechol), initially methanolsoluble, became purple-coloured with a defied insolubility under aerobic conditions. Intramolecular cross-linking is viewed as a possible explanation for the observed insolubility of the obtained resin; that is, either benzene rings of two moieties undergo an intramolecular Pummerer reaction. A mechanism of the deportation of the redox polymers seems to be substituent-dependent polymer precursors. Indeed. poly(3-vinylcatechol) remained methanol-soluble for months with a faint pink colour. Redox midpotentials of poly(3-vinylcatechol) were established to be 707 mV at 23 °C, while that of catechol was found to be 764 mV under the same conditions.

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نویسندگان: 

JACOB C. | ANWAR A.

نشریه: 

PHYSIOLOGY OF PLANTS

اطلاعات دوره: 
  • سال: 

    2008
  • دوره: 

    133
  • شماره: 

    -
  • صفحات: 

    0-0
تعامل: 
  • استنادات: 

    1
  • بازدید: 

    151
  • دانلود: 

    0
کلیدواژه: 
چکیده: 

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بازدید 151

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نویسندگان: 

LIU H. | COLAVITTI R. | ROVIRA I.I.

نشریه: 

CIRCULATION RESEARCH

اطلاعات دوره: 
  • سال: 

    2005
  • دوره: 

    97
  • شماره: 

    10
  • صفحات: 

    967-974
تعامل: 
  • استنادات: 

    1
  • بازدید: 

    180
  • دانلود: 

    0
کلیدواژه: 
چکیده: 

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بازدید 180

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نویسندگان: 

اطلاعات دوره: 
  • سال: 

    2017
  • دوره: 

    8
  • شماره: 

    -
  • صفحات: 

    87-87
تعامل: 
  • استنادات: 

    1
  • بازدید: 

    76
  • دانلود: 

    0
کلیدواژه: 
چکیده: 

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بازدید 76

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نویسندگان: 

Ullah Rabid

اطلاعات دوره: 
  • سال: 

    2023
  • دوره: 

    5
  • شماره: 

    4
  • صفحات: 

    466-476
تعامل: 
  • استنادات: 

    0
  • بازدید: 

    20
  • دانلود: 

    0
چکیده: 

Zinc ferrite (ZnFe2O4) is one of the famous and widely studied photocatalysts with band-gap in the visible region.  ZnFe2O4 has emerged as a promising photocatalyst due to its unique properties and versatile applications. This review aims to provide an overview of the properties, synthesis methods, and photocatalytic performance of zinc ferrite. It also explores the diverse applications of zinc ferrite composites as catalysts, highlighting their performance as photocatalysts. The catalyst possesses a spinal fine crystalline structure and can be prepared by various methods such as combustion, hydrothermal, sol-gel, and co-precipitation. Zinc ferrite by nature is a superparamagnetic semiconductor that has been used for the degradation of numerous organic dyes in the past. ZnFe2O4 is particularly effective in harnessing light energy and actively supports photocatalytic-redox reactions.

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نویسندگان: 

NAKAMURA H. | NAKAMURA K. | YODOI J.

اطلاعات دوره: 
  • سال: 

    1997
  • دوره: 

    15
  • شماره: 

    -
  • صفحات: 

    351-369
تعامل: 
  • استنادات: 

    1
  • بازدید: 

    88
  • دانلود: 

    0
کلیدواژه: 
چکیده: 

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بازدید 88

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نویسندگان: 

MAULIK N.

اطلاعات دوره: 
  • سال: 

    2002
  • دوره: 

    4
  • شماره: 

    5
  • صفحات: 

    783-784
تعامل: 
  • استنادات: 

    1
  • بازدید: 

    136
  • دانلود: 

    0
کلیدواژه: 
چکیده: 

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بازدید 136

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اطلاعات دوره: 
  • سال: 

    2014
  • دوره: 

    8
تعامل: 
  • بازدید: 

    118
  • دانلود: 

    0
چکیده: 

AVAILABILITY OF SULFUR AS A BY-PRODUCT HAS CONSIDERABLY GROWN IN MANY COUNTRIES DUE TO THE INCREASE IN NUMBER OF OIL AND GAS INDUSTRIES AND POSE MAJOR CHALLENGES TO THE ENVIRONMENTAL PROTECTION. THEREFORE, INVESTIGATION FOR NEW APPLICATIONS OF SULFUR TO MAKE ADDED VALUE SEEMS TO BE INEVITABLE.BITUMEN HAS BEEN WIDELY USED IN ROAD PAVEMENT AS THE BINDER OF AGGREGATE. IN THE PAVING INDUSTRIES, SOME VOLUME OR WEIGHT PERCENTAGE OF BITUMEN CAN BE REPLACED BY THE ADDITION OF MOLTEN SULFUR OR SULFUR PELLETS. THIS MIXTURE, REFERRED TO AS SULFUR-EXTENDED-ASPHALT OR SEA FOR SHORT, HAS A GREAT EFFECT ON THE PROPERTIES OF RESULTING ASPHALT MIXTURE. SEA MIXTURES HAVE REPORTED TO OFFER ENHANCED CHARACTERISTICS AND PERFORMANCE IN THE PAST.IN THIS PRESENT WORK VARIOUS SEA MIXTURES HAVE BEEN PREPARED AND THE PERFORMANCE OF THE PRODUCED ASPHALT AND THE ODOR ABSORPTION POTENTIALS OF VARIOUS ADDITIVES HAVE BEEN EXAMINED. THE PRELIMINARY RESULTS HAVE INDICATED THAT THE UNPLEASANT AND HARMFUL SULPHUR FUMES CAN BE ELIMINATED SUBSTANTIALLY DURING THE SEA PREPARATION.

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